Absorption spectroscopy and 组合数学 (Fall 2017)/Problem Set 1: Difference between pages

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'''Absorption [[spectroscopy]] '''is a technique used to find out what makes up a sample of a [[substance]] – in other words, a chemical [[analysis]].<ref>http://www.andor.com/learning-academy/absorption-transmission-reflection-spectroscopy-an-introduction-to-absorption-transmission-reflection-spectroscopy</ref>
== Problem 1 ==
#有<math>k</math>种不同的明信片,每种明信片有无限多张,寄给<math>n</math>个人,每人一张,有多少种方法?
#有<math>k</math>种不同的明信片,每种明信片有无限多张,寄给<math>n</math>个人,每人一张,每个人必须收到不同种类的明信片,有多少种方法?
#有<math>k</math>种不同的明信片,每种明信片有无限多张,寄给<math>n</math>个人,每人收到<math>r</math>张不同的明信片(但不同的人可以收到相同的明信片),有多少种方法?
#只有一种明信片,共有<math>m</math>张,寄给<math>n</math>个人,全部寄完,每个人可以收多张明信片或者不收明信片,有多少种方法?
#有<math>k</math>种不同的明信片,其中第<math>i</math>种明信片有<math>m_i</math>张,寄给<math>n</math>个人,全部寄完,每个人可以收多张明信片或者不收明信片,有多少种方法?


When a full spectrum of light (light with all the colours, like light from the sun) passes through the sample (which is often a gas) some specific colours do not show up on the other side. These colours of light are being absorbed by the sample. An image is created of the spectrum of light with black breaks where the light has been absorbed. These breaks are called absorption lines, and every element has its characteristic pattern of absorption lines.
== Problem 2 ==
Find the number of ways to select <math>2n</math> balls from <math>n</math> identical blue balls, <math>n</math> identical red balls and <math>n</math> identical green balls.
* Give a combinatorial proof for the problem.
* Give an algebraic proof for the problem.


On an atomic scale, this happens because of the [[Electron|electrons]] in the [[atom|atoms]] of the sample - an electron can absorb light to gain energy. From experiments, electrons only ever absorb certain amounts of energy, suggesting an electron's energy must fit onto set, quantised, discrete ''energy levels''.<ref>http://hyperphysics.phy-astr.gsu.edu/hbase/hframe.html</ref> The process of an electron going to a higher energy level is called ''excitation''. For any atom of a particular element, the energy needed to excite an electron from one specific energy level to another will be the same. This is important because it allows us to compare the absorption lines of say, the atmosphere of a far away planet, to the absorption lines of elements we know to exist in a lab. We can then reach a conclusion about what the distant planet's atmosphere may be made of.
== Problem 3 ==
*一个长度为<math>n</math>的“山峦”是如下由<math>n</math>个"/"和<math>n</math>个"\"组成的,从坐标<math>(0,0)</math>到<math>(0,2n)</math>的折线,但任何时候都不允许低于<math>x</math>轴。例如下图:


The missing colours give us information about the energy of the photons that cause excitation. Note that the energy gained by the excited electron is equal to the energy of the incident [[photon]] (a particle of light), so only photons with fitting energies will cause an excitation. The energy of a photon is proportional to its frequency:'' ''
    /\
  /  \/\/\    /\/\
  /        \/\/    \/\/\
  ----------------------
:长度为<math>n</math>的“山峦”有多少?


<math display="block">E=hf</math>
*一个长度为<math>n</math>的“地貌”是由<math>n</math>个"/"和<math>n</math>个"\"组成的,从坐标<math>(0,0)</math>到<math>(0,2n)</math>的折线,允许低于<math>x</math>轴。长度为<math>n</math>的“地貌”有多少?


Where ''E'' is the energy of a photon, ''h'' is Planck's constant (a constant is a set number that doesn't change) and ''f'' is the frequency of the photon. Since a colour can be described as a specific frequency of light, this is why the black breaks can be used to identify element(s) which the light is passing through.
== Problem 4==
[[File:Spectral lines absorption.png|centre|frameless|342x342px]]
李雷和韩梅梅竞选学生会主席,韩梅梅获得选票 <math>p</math> 张,李雷获得选票 <math>q</math> 张,<math>p>q</math>。我们将总共的 <math>p+q</math> 张选票一张一张的点数,有多少种选票的排序方式使得在整个点票过程中,韩梅梅的票数一直高于李雷的票数?等价地,假设选票均匀分布的随机排列,以多大概率在整个点票过程中,韩梅梅的票数一直高于李雷的票数。
The intensity of the absorption varies as a function of frequency, and this variation is the '''absorption spectrum'''.


In [[chemistry]], the technique is used to detect and measure [[wikt:concentration|concentration]]s of a particular [[metal]] [[chemical element|element]] within a [[solution]]. The  scientists atomise the sample (make it turn to individual atoms) and then see what light wavelengths it absorbs. Each type of chemical (element) absorbs a particular wavelength, so scientists can tell which chemicals are in the sample. Every element has a different atomic absorption spectrum because of the different light wavelengths it absorbs.
==Problem 5==
A <math>2\times n</math> rectangle is to be paved with <math>1\times 2</math> identical blocks and <math>2\times 2</math> identical blocks. Let <math>f(n)</math> denote the number of ways that can be done. Find a recurrence relation for <math>f(n)</math>, solve the recurrence relation.


[[File:Sodium in atmosphere of exoplanet HD 209458.jpg|thumb|center|500px|The first direct detection and chemical analysis of the [[atmosphere]] of an planet outside our solar system. Sodium filters the alien star  light of [[HD 209458]] as the hot Jupiter planet passes in front. The process and absorption spectrum are illustrated above. Image Credit: A. Feild, [[STScI]] and [[NASA]] website.]]
== Problem 6 ==
Let <math>a_n</math> be a sequence of numbers satisfying the recurrence relation:
:<math>p a_n+q a_{n-1}+r a_{n-2}=0</math>
with initial condition <math>a_0=s</math> and <math>a_1=t</math>, where <math>p,q,r,s,t</math> are constants such that <math>{p}+q+r=0</math>, <math>p\neq 0</math> and <math>s\neq t</math>. Solve the recurrence relation.


==References==
== Problem 7 ==
{{reflist}}
* 令<math>s_n</math>表示长度为<math>n</math>,没有2个连续的1的二进制串的数量,即
*:<math>s_n=|\{x\in\{0,1\}^n\mid \forall 1\le i\le n-1, x_ix_{i+1}\neq 11\}|</math>。
:求 <math>s_n</math>。


*令<math>t_n</math>表示长度为<math>n</math>,没有3个连续的1的二进制串的数量,即
*:<math>t_n=|\{x\in\{0,1\}^n\mid \forall 1\le i\le n-2, x_ix_{i+1}x_{i+2}\neq 111\}|</math>。
*#给出计算<math>t_n</math>的递归式,并给出足够的初始值。
*#计算<math>t_n</math>的生成函数<math>T(x)=\sum_{n\ge 0}t_n x^n</math>,给出生成函数<math>T(x)</math>的闭合形式。


{{physics-stub}}
注意:只需解生成函数的闭合形式,无需展开。
 
[[Category:Spectroscopy‏]]

Revision as of 13:09, 17 September 2017

Problem 1

  1. [math]\displaystyle{ k }[/math]种不同的明信片,每种明信片有无限多张,寄给[math]\displaystyle{ n }[/math]个人,每人一张,有多少种方法?
  2. [math]\displaystyle{ k }[/math]种不同的明信片,每种明信片有无限多张,寄给[math]\displaystyle{ n }[/math]个人,每人一张,每个人必须收到不同种类的明信片,有多少种方法?
  3. [math]\displaystyle{ k }[/math]种不同的明信片,每种明信片有无限多张,寄给[math]\displaystyle{ n }[/math]个人,每人收到[math]\displaystyle{ r }[/math]张不同的明信片(但不同的人可以收到相同的明信片),有多少种方法?
  4. 只有一种明信片,共有[math]\displaystyle{ m }[/math]张,寄给[math]\displaystyle{ n }[/math]个人,全部寄完,每个人可以收多张明信片或者不收明信片,有多少种方法?
  5. [math]\displaystyle{ k }[/math]种不同的明信片,其中第[math]\displaystyle{ i }[/math]种明信片有[math]\displaystyle{ m_i }[/math]张,寄给[math]\displaystyle{ n }[/math]个人,全部寄完,每个人可以收多张明信片或者不收明信片,有多少种方法?

Problem 2

Find the number of ways to select [math]\displaystyle{ 2n }[/math] balls from [math]\displaystyle{ n }[/math] identical blue balls, [math]\displaystyle{ n }[/math] identical red balls and [math]\displaystyle{ n }[/math] identical green balls.

  • Give a combinatorial proof for the problem.
  • Give an algebraic proof for the problem.

Problem 3

  • 一个长度为[math]\displaystyle{ n }[/math]的“山峦”是如下由[math]\displaystyle{ n }[/math]个"/"和[math]\displaystyle{ n }[/math]个"\"组成的,从坐标[math]\displaystyle{ (0,0) }[/math][math]\displaystyle{ (0,2n) }[/math]的折线,但任何时候都不允许低于[math]\displaystyle{ x }[/math]轴。例如下图:
   /\
  /  \/\/\    /\/\
 /        \/\/    \/\/\
 ----------------------
长度为[math]\displaystyle{ n }[/math]的“山峦”有多少?
  • 一个长度为[math]\displaystyle{ n }[/math]的“地貌”是由[math]\displaystyle{ n }[/math]个"/"和[math]\displaystyle{ n }[/math]个"\"组成的,从坐标[math]\displaystyle{ (0,0) }[/math][math]\displaystyle{ (0,2n) }[/math]的折线,允许低于[math]\displaystyle{ x }[/math]轴。长度为[math]\displaystyle{ n }[/math]的“地貌”有多少?

Problem 4

李雷和韩梅梅竞选学生会主席,韩梅梅获得选票 [math]\displaystyle{ p }[/math] 张,李雷获得选票 [math]\displaystyle{ q }[/math] 张,[math]\displaystyle{ p\gt q }[/math]。我们将总共的 [math]\displaystyle{ p+q }[/math] 张选票一张一张的点数,有多少种选票的排序方式使得在整个点票过程中,韩梅梅的票数一直高于李雷的票数?等价地,假设选票均匀分布的随机排列,以多大概率在整个点票过程中,韩梅梅的票数一直高于李雷的票数。

Problem 5

A [math]\displaystyle{ 2\times n }[/math] rectangle is to be paved with [math]\displaystyle{ 1\times 2 }[/math] identical blocks and [math]\displaystyle{ 2\times 2 }[/math] identical blocks. Let [math]\displaystyle{ f(n) }[/math] denote the number of ways that can be done. Find a recurrence relation for [math]\displaystyle{ f(n) }[/math], solve the recurrence relation.

Problem 6

Let [math]\displaystyle{ a_n }[/math] be a sequence of numbers satisfying the recurrence relation:

[math]\displaystyle{ p a_n+q a_{n-1}+r a_{n-2}=0 }[/math]

with initial condition [math]\displaystyle{ a_0=s }[/math] and [math]\displaystyle{ a_1=t }[/math], where [math]\displaystyle{ p,q,r,s,t }[/math] are constants such that [math]\displaystyle{ {p}+q+r=0 }[/math], [math]\displaystyle{ p\neq 0 }[/math] and [math]\displaystyle{ s\neq t }[/math]. Solve the recurrence relation.

Problem 7

  • [math]\displaystyle{ s_n }[/math]表示长度为[math]\displaystyle{ n }[/math],没有2个连续的1的二进制串的数量,即
    [math]\displaystyle{ s_n=|\{x\in\{0,1\}^n\mid \forall 1\le i\le n-1, x_ix_{i+1}\neq 11\}| }[/math]
[math]\displaystyle{ s_n }[/math]
  • [math]\displaystyle{ t_n }[/math]表示长度为[math]\displaystyle{ n }[/math],没有3个连续的1的二进制串的数量,即
    [math]\displaystyle{ t_n=|\{x\in\{0,1\}^n\mid \forall 1\le i\le n-2, x_ix_{i+1}x_{i+2}\neq 111\}| }[/math]
    1. 给出计算[math]\displaystyle{ t_n }[/math]的递归式,并给出足够的初始值。
    2. 计算[math]\displaystyle{ t_n }[/math]的生成函数[math]\displaystyle{ T(x)=\sum_{n\ge 0}t_n x^n }[/math],给出生成函数[math]\displaystyle{ T(x) }[/math]的闭合形式。

注意:只需解生成函数的闭合形式,无需展开。