Carbonation

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File:Burren karst.jpg
Karst landscape of the Burren

Carbonation is the process of carbon dioxide dissolving in a liquid. For example, carbon dioxide is added to flavored water under pressure to make it "fizz" as a carbonated soft drink.

Geology

When rain passes through the atmosphere, it takes in or mixes with carbon dioxide, turning it into a weak carbonic acid. When the rain falls in limestone, it dissolves the calcium carbonate in the rock, turning it into calcium bicarbonate. This basically dissolves the rock. Holes and large cracks can form in the rock, which are called grikes, or in German ship docking "kruftkarren".[1] The limestone that is left is called clint.[2] In a large karst area which is a large area of limestone, there are a lot of big grikes. If a stream or river passes through it, it could be swallowed up by a hole called a swallow hole. It can go through a series of underground caves and may appear on the surface again. An example of a karst area is the Burren, in County Clare, Ireland.[3]

Chemistry

Template:Complex Carbon dioxide is weakly soluble in water, therefore it separates into a gas. The process of carbon dioxide bubbling out (effervescing) from a solution is represented by the following chemical reaction. This shows aqueous carbonic acid converts to carbon dioxide and water:

[math]\displaystyle{ \mbox{H}_2\mbox{CO}_3 \longrightarrow \mbox{H}_2\mbox{O} + \mbox{CO}_2 }[/math]

Biochemistry

Template:Complex Carbonation also describes the incorporation of carbon dioxide into chemical compounds. Carbon-based life originates from a carbonation reaction that is most often catalysed by the enzyme RuBisCO. This carbonation process is so important that a significant fraction of leaf mass consists of this carbonating enzyme.[4]

File:CO2Fixn.png
Carbonation of ribulose bisphosphate is the starting point of the incorporation of carbon dioxide into the biosphere.

References

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  1. Template:Cite web
  2. Template:Cite web
  3. Template:Cite web
  4. Stryer, Lubert; Berg, JeremyMark; Tymoczko, John L. Biochemistry, 5th Ed. W.H. Freeman, San Francisco, 2002. ISBN 0-7167-3051-0